1-[(E)-(3,4-Dimethylisoxazol-5-yl)iminomethyl]-2-naphthol
نویسندگان
چکیده
The title Schiff base compound, C(16)H(14)N(2)O(2), has been synthesized by the reaction of 5-amino-3,4-dimethyl-isoxazole and 2-hydr-oxy-1-naphthaldehyde. The dihedral angle between the isoxazole ring and the napthyl ring system is 3.29 (7)°. The mol-ecule adopts an E configuration about the central C=N double bond. Intra-molecular O-H⋯N hydrogen bonding generates an S(6) ring motif. In the crystal structure, π-π inter-actions are observed involving the isoxazole ring and the substituted benzene ring of the naphthyl unit, with centroid-centroid distances of 3.5200 (10) Å.
منابع مشابه
2-[(E)-(3,4-Dimethylisoxazol-5-yl)iminomethyl]phenol
The title compound, C(12)H(12)N(2)O(2), has been synthesized by the reaction of 5-amino-3,4-dimethyl-isoxazole and salicyladehyde. The mol-ecule adopts an E configuration about the central C=N double bond. The dihedral angle between the isoxazole and phenyl rings is 4.2 (2)° and an intra-molecular O-H⋯N hydrogen bond generates an S(6) ring motif. The crystal studied was a non-merohedral twin wi...
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متن کامل1-[(E)-(2-Methyl-3-nitrophenyl)iminomethyl]-2-naphthol
The title Schiff base compound, C(18)H(14)N(2)O(3), has an inter-mediate state between NH and OH tautomers. The mol-ecular structure is stabilized by an O-H⋯N hydrogen bond. The dihedral angle between the naphthalene ring system and the benzene ring is 37.44 (5)°.
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عنوان ژورنال:
دوره 66 شماره
صفحات -
تاریخ انتشار 2010